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  1. Jan 26, 2023 · The couple met on the set of "Pushing Tin" in 1999 and married in 2000, but divorced in 2003. They grew apart as people and had nothing to say to each other, according to Jolie.

    • Delilah Gray
    • Jonny Lee Miller
    • Jenny Shimizu
    • Billy Bob Thornton
    • Val Kilmer
    • Brad Pitt
    • The Weeknd

    Jolie met English actor Jonny Lee Miller while working on the 1995 film Hackers. The two got married in a very small civil ceremony in 1996, but separated only a year later when their busy schedules kept them apart. The Maleficentactress filed for divorce in 1999, which was finalized the same year. Despite their split, Jolie has spoken fondly of Mi...

    Jolie met her Foxfire costar Jenny Shimizu around the same time she met Miller. The pair spent a lot of time together in 1996, and Jolie reportedly told Girlfriends Magazine in 1997, per InStyle, that the model "could have been a deep love" for her. "I probably would have married Jenny Shimizu if I hadn't married my husband," she added. "I fell in ...

    In 1999, Jolie met actor Billy Bob Thornton while filming Pushing Tin. The pair eloped the following year in Las Vegas, shortly after Thornton abruptly ended his engagement to actress Laura Dern. Perhaps the most iconic moment of Jolie and Thornton's marriage came in 2001 when they were were spotted wearing vials of each other's blood. Jolie even g...

    Jolie and Val Kilmer sparked romance speculation while working on their 2004 film Alexander, in which the pair played the feuding mother and father of Alexander the Great. While there's no evidence they dated at the time, Kilmer admitted he had a crush on Jolie in his 2020 memoir I'm Your Huckleberry. "I couldn't wait to kiss Angie, buy her a Gulfs...

    Jolie met Pitt when they worked together on 2005's Mr. and Mrs. Smith. At the time, Pitt was married to Friends actress Jennifer Aniston, though the two announced their separation in January 2005. (Pitt and Aniston's divorce was finalized later that year.) In July, Pitt accompanied Jolie to Ethiopia to adopt her second child, Zahara. By January, Jo...

    Jolie and The Weeknd sparked romance rumors in 2021 when they were spotted sharing not one but two dinners out together. A source told PEOPLE the couple had known each other "for some time" and shared a bond over their connection to Ethiopia — the R&B crooner had partnered with the World Food Program US to donate $1 million in relief efforts in the...

    • Emy Lacroix
  2. Jun 15, 2018 · After more than a decade, actor Billy Bob Thornton shared what led to his divorce from actress Angelina Jolie in 2003. Thornton has married six times, but his relationship with Jolie—who is...

  3. Nov 10, 2016 · Not easy, at least according to Billy Bob Thornton, the actor and Oscar-winning screenwriter who was married to Jolie from 2000 to 2003. Though the difficulty was no fault of Jolie’s,...

  4. Oct 22, 2014 · Billy Bob Thornton gets candid on his three-year marriage to Angelina Jolie. Though we bet plenty of men would do just about anything for a chance with Dame Angelina Jolie, apparently,...

  5. Next to Pamela and Tommy, Angelina Jolie and Billy Bob Thornton’s marriage was one of intrigue. Who, after all, in their right minds cruised around with vials of each other’s blood as necklaces? Jolie seemed a wild child – and if you ask Chelsey Handler, she still is.

  6. Jan 24, 2019 · They share a 14-year-old daughter, Bella, together. A look back at the relationship between Y2k's wildest couple.