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Doping with 10 mM HCl
- Ice-fourteen (ice XIV) is the proton-ordered form of ice-twelve, formed by doping with 10 mM HCl (about one molecule to every 5000 molecules of water; as DCl with D 2 O) below 118 K and at 1.2 GPa to facilitate the phase transition.
vitroid.github.io/water-science/water/ice_xiv.html
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What are ice XIII and XIV?
How does ice XIX Form?
What is ice XI?
What is the crystalline phase of ice XIX?
Ice XI is the hydrogen-ordered form of the ordinary form of ice. The total internal energy of ice XI is about one sixth lower than ice I h , so in principle it should naturally form when ice I h is cooled to below 72 K .
May 26, 2021 · Ice XIX definitely forms a \(\sqrt{2}\times \sqrt{2}\times 1\) super-cell with twice the unit cell volume of ice VI (and ice XV). Neither orthorhombic nor tetragonal unit cells can be ruled...
- Thomas C. Hansen
- hansen@ill.fr
- 2021
Ice-fourteen (ice XIV) is the proton-ordered form of ice-twelve, formed by doping with 10 mM HCl (about one molecule to every 5000 molecules of water; as DCl with D 2 O) below 118 K and at 1.2 GPa to facilitate the phase transition [1002].
Mar 24, 2006 · Ice XIV, at around 160 degrees Celcius the coldest ice ever found, has a simple molecular structure. Credit: Science. Scientists have discovered two previously unknown forms of ice, frozen...
- Science X
Feb 18, 2021 · More than 10 years ago, researchers at the University of Innsbruck produced a hydrogen-ordered variant of this ice, which found its way into textbooks as ice XV. By changing the manufacturing ...
- University of Innsbruck
pressure form (also known as ice-thirteen) involves hydrogen atoms equally-spaced between the oxygen atoms [84] (like ice-ten) in a distorted hexagonal close packed structure whereas (b) the lower pressure, low temperature, form uses the incorporation of hydroxide defect doping (and
May 26, 2021 · Ice VI is a hydrogen-disordered phase of ice that crystallises from liquid water in the 0.6–2.2 GPa pressure range 9. Its structure consists of two interlocking hydrogen-bonded networks and ...